Implementation of a choline bis(trifluoromethylsulfonyl)imide aqueous electrolyte for low temperature EDLCs enabled by a cosolvent
[ 1 ] Instytut Chemii i Elektrochemii Technicznej, Wydział Technologii Chemicznej, Politechnika Poznańska | [ P ] pracownik
2022
artykuł naukowy
angielski
- Carbon/carbon capacitor
- Choline bis(trifluoromethylsulfonyl)imide
- Low-temperature
- Aqueous electrolyte
- Cosolvent electrolyte
- Methanol
- Isopropanol
EN We report a carbon/carbon capacitor based on micro/mesoporous carbon electrodes with cost-effective and eco-friendly aqueous choline bis(trifluoromethylsulfonyl)imide (ChTFSI) electrolyte with a cosolvent enabling low-temperature operation down to −30 °C. For this purpose, a MgO-templated hierarchical carbon (MP98B) with an average mesopore diameter of 3.5 nm was prepared by pyrolysis of magnesium citrate hydrate at 900 °C. To reach lower temperatures, the melting point and viscosity of the aqueous electrolyte were reduced by mixing water (W) with an organic solvent (methanol, M, or isopropanol, I) of high dielectric constant and low viscosity. 5 mol kg−1 (5 m) ChTFSI in an optimized volume fraction of cosolvent, M0.75W0.25, and I0.75W0.25, showed the highest conductivity; the higher conductivity in M0.75W0.25 (22.8 and 3.1 mS cm−1 at 20 and −30 °C, respectively) than in I0.75W0.25 (8.5 and 0.5 mS cm−1 at 20 and −30 °C, respectively) is attributed to the lower viscosity of the M0.75W0.25 solution. The electrochemical stability window (ESW) of 5 m ChTFSI in M0.75W0.25 and I0.75W0.25 (1.6 V) on an MP98B electrode was determined by applying the S-method. Meanwhile, by adjusting the mass ratio of the two electrodes, a MP98B/MP98B capacitor using the 5 m electrolyte in M0.75W0.25 could operate with a good life span up to 1.6 V while exhibiting a better charge propagation, greater specific capacitance, and higher specific energy than in I0.75W0.25.
26.02.2022
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