Teeth and bones micro-slurries introduction to MIP OES for elements simultaneous quantification
[ 1 ] Instytut Chemii i Elektrochemii Technicznej, Wydział Technologii Chemicznej, Politechnika Poznańska | [ SzD ] doktorant ze Szkoły Doktorskiej | [ P ] pracownik
2023
artykuł naukowy
angielski
- Slurry sampling
- Teeth and bones samples
- Micro-volume sample injection
- Simultaneous metals quantification
- Microwave induced plasma
- Optical emission spectrometry
EN This study aims development of new, rapid and direct method for simultaneous multi-elemental determination in micro-volume slurried samples of teeth and bones. The method proposed allow for direct, without prior sample decomposition, injection of 15 μL of slurries (Bone Meal NIST 1486, deciduous human and dog teeth) into microwave induced plasma optical emission spectrometer (MIP OES) and determination of Ca, Cu, Fe, K, Mg, Mn, Na, Pb, Sr and Zn. The optimization procedures were undertaken (univariate and simplex methods) to achieve the best values of parameters influencing the analytical signals. Minimum dead volume, high nebulization and slurry transport efficiency were obtained by using on-axis low-volume spray chamber/v-groove pneumatic nebulizer interface for 15 μL slurry injection in discontinues mode (at 1.2 mL min− 1 pump speed). Analytical parameters of the proposed method were assessed by determination of the limits of detection (LODs), absolute detection limit and precision (RSDs). The obtained LODs were appropriate (in the range of mg/ kg) for the determination of the elements in the standard reference material (Bone Meal NIST 1486) for validation procedure and successful application in two real samples (deciduous human and dog teeth).
21.03.2023
115129-1 - 115129-8
Article number: 115129
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