2022

Applied Surface Science

Journal year: 2022 | Journal volume: vol. 590

scientific article

english

EN In this paper, we report on the first experimental study on the impact of neutron radiation on quasi-free-standing (QFS) graphene. For this purpose, we have fabricated hydrogen-intercalated QFS graphene on semiinsulating high-purity 4H-SiC(0001), passivated it with an Al2O3 layer, and exposed it to a fast-neutron fluence of ≈ 6.6 × 1017 cm−2. The results have shown that the graphene sheet is only moderately affected by the neutron radiation with the estimated defect density of ≈ 4 × 1010 cm−2. The low structural damage allowed the Al2O3/graphene/SiC system to maintain its electrical properties and an excellent sensitivity to magnetic fields characteristic of QFS graphene. Consequently, our findings suggest that the system may be a promising platform for magnetic diagnostics in magnetic-confinement fusion reactors. However, the scope of its use should be a subject of further study. In this context, we have explored possible modes of damage and have concluded that the main factor that affects the electrical parameters of the structure is the impact of neutrons on the layer of hydrogen atoms saturating the SiC(0001) surface. We have shown, employing density functional theory (DFT) computations, that damage to the intercalating layer could lower hole concentration in graphene via reduced charge polarization and local coupling on the interface.

11.03.2022

152992 - 1 - 152992 - 11

10.1016/j.apsusc.2022.152992

https://www.sciencedirect.com/science/article/pii/S0169433222005608?via%3Dihub

Article Number: 152992

Czasopismo hybrydowe

140

6,7