Thermal and Morphological Analysis of Linear Low-Density Polyethylene Composites Containing D-limonene/β-cyclodextrin for Active Food Packaging
[ 1 ] Instytut Technologii Materiałów, Wydział Inżynierii Mechanicznej, Politechnika Poznańska | [ P ] employee | [ S ] student
2023
scientific article
english
- linear low-density polyethylene
- polymer composite
- food packaging
EN Composites made of linear low-density polyethylene (LLDPE) and β-cyclodextrin/d-limonene inclusion complex (CD-lim) were prepared by melt extrusion to develop a novel food packaging material. Scanning electron microscopy evidenced a fairly good dispersion of the filler within the polymeric matrix. Infrared spectroscopy coupled with thermogravimetric analysis confirmed the presence of CD-lim in the composites, proving that the applied technology of including the essential oil within β-CD cages allows for preventing a sizable loss of d-limonene despite a high temperature and shear applied upon extrusion processing. Moreover, the influence of the filler on the thermal properties of PE was assessed. It was found that the cyclodextrin-based inclusion complex significantly fastens the crystallization path of the polyethylene matrix with an improved crystallization rate of the PE/CD-lim composites compared to the neat polymer.
26.01.2023
1220-1 - 1220-11
Article Number: 1220
CC BY (attribution alone)
open journal
final published version
at the time of publication
140
4,2