Development of novel thin-film solid-phase microextraction materials based on deep eutectic solvents for preconcentration of trace amounts of parabens in surface waters
[ 1 ] Instytut Chemii i Elektrochemii Technicznej, Wydział Technologii Chemicznej, Politechnika Poznańska | [ P ] pracownik
2022
artykuł naukowy
angielski
- deep eutectic solvent
- mesh support
- parabens
- thin-film solid-phase microextraction
EN A green and sensitive thin-film solid-phase microextraction method based on deep eutectic solvent was developed that enables simultaneous isolation, preconcentration, and determination of parabens in surface waters. Six new deep eutectic solvents were synthesized and used directly to prepare thin-film coatings on a stainless steel mesh support. Among the compounds obtained, the highest efficiency in the extraction of parabens was found for a material consisting of trihexyltetradecylphosphonium chloride and n-docosanol in a molar ratio of 1:2. For the proposed method, parameters affecting the extraction efficiency of parabens, such as the coating material, the desorption solvent, the volume of the sample, the pH of the sample, the extraction and desorption time, and the saltingout effect, were optimized. Under optimal conditions, the proposed method allowed us to achieve good precision between 3.6 and 6.5% and recovery ranging from 68.1 to 91.4%. The limits of detection range from 0.018 to 0.055 ng/mL.
09.02.2022
1374 - 1384
CC BY (uznanie autorstwa)
otwarte czasopismo
ostateczna wersja opublikowana
09.02.2022 (Data domniemana)
w momencie opublikowania
publiczny
70
3,1