2022

Gels

Rocznik: 2022 | Tom: vol. 8 | Numer: iss. 8

artykuł naukowy

angielski

EN first_pagesettingsOrder Article Reprints Open AccessArticle The Influence of Aminoalcohols on ZnO Films’ Structure by Ewelina Nowak 1,*ORCID,Edyta Chłopocka 1,†ORCID,Mirosław Szybowicz 1,†ORCID,Alicja Stachowiak 2,†ORCID,Wojciech Koczorowski 2,†ORCID,Daria Piechowiak 3,†ORCID andAndrzej Miklaszewski 3,†ORCID 1 Institute of Materials Research and Quantum Engineering, Faculty of Materials Engineering and Technical Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznań, Poland 2 Institute of Physics, Faculty of Materials Engineering and Technical Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznań, Poland 3 Institute of Materials Engineering, Faculty of Materials Engineering and Technical Physics, Poznań University of Technology, Piotrowo 3, 60-965 Poznań, Poland * Author to whom correspondence should be addressed. † These authors contributed equally to this work. Gels 2022, 8(8), 512; https://doi.org/10.3390/gels8080512 Received: 15 June 2022 / Revised: 12 August 2022 / Accepted: 16 August 2022 / Published: 17 August 2022 (This article belongs to the Special Issue Gel-Based Noble Composite Nanostructure Materials and Their Potential Applications) Download Browse Figures Review Reports Versions Notes Abstract Preparing structures with the sol-gel method often requires control of the basal plane of crystallites, crystallite structures, or the appearance of the voids. One of the critical factors in the formation of a layer are additives, such as aminoalcohols, which increase the control of the sol formation reaction. Since aminoalcohols differ in boiling points and alkalinity, their selection may play a significant role in the dynamics of structure formation. The main aim of this work is to examine the properties of ZnO layers grown using different aminoalcohols at different concentration rates. The layers were grown on various substrates, which would provide additional information on the behavior of the layers on a specific substrate, and the mixture was annealed at a relatively low temperature (400 °C). The research was conducted using monoethanolamine (MEA) and diethanolamine (DEA). The aminoalcohols were added to the solutions in equal concentrations. The microscopic image of the structure and the size of the crystallites were determined using micrographs. X-ray diffractometry and Raman spectroscopy were used for structural studies, phase analysis and to establish the purity of the obtained films. UV-vis absorption and photoluminescence were used to evaluate structural defects. This paper shows the influence of the stabilizer on the morphology of samples and the influence of the morphology and structure on the optical properties. The above comparison may allow the preparation of ZnO samples for specific applications.

17.08.2022

512-1 - 512-19

10.3390/gels8080512

https://www.mdpi.com/2310-2861/8/8/512

Article Number: 512

CC BY (uznanie autorstwa)

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