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Article


Title

New way to obtain the poly(L-lactide-co-D,L-lactide) blend filled with nanohydroxyapatite as biomaterial for 3D-printed bone-reconstruction implants

Authors

[ 1 ] Instytut Technologii Materiałów, Wydział Inżynierii Mechanicznej, Politechnika Poznańska | [ 2 ] Instytut Technologii i Inżynierii Chemicznej, Wydział Technologii Chemicznej, Politechnika Poznańska | [ P ] employee

Scientific discipline (Law 2.0)

[2.7] Materials engineering
[2.8] Mechanical engineering
[6.5] Chemical sciences

Year of publication

2022

Published in

European Polymer Journal

Journal year: 2022 | Journal volume: vol. 165

Article type

scientific article

Publication language

english

Keywords
EN
  • poly(L-lactide-co-D
  • L-lactide)
  • nanohydroxyapatite
  • biocomposite
  • co-rotating twin-screw extrusion
  • bone-fixation material
Abstract

EN A novel, bone-reconstruction dedicated polymeric-nanohydroxyapatite material has been prepared for 3D-printed implant. The composites of poly(L-lactide-co-D,L-lactide) (PLDLLA) and nanosized hydroxyapatite were prepared by a co-rotating twin-screw extrusion. Structural properties of the filler and polymeric blends were characterized by XRD (X-ray Powder Diffraction), SEM (Scanning Electron Microscopy), and EDS mapping (energy dispersive spectroscopy), FT-IR (Fourier-transformed infrared spectroscopy), and NMR (Nuclear Magnetic Resonance) technics. Molar masses of the composites at various preparation steps were also investigated. The structural studies and thermogravimetric analysis proved a successful preparation of the nanohydroxyapatite and its nanocomposites. Mechanical results in conjunction with density values, reported as close to human bone, evidenced usability of this novel material for internal bone fixation implant. Contact angle analysis showed favored growth of tissue on the biocomposite containing 10 wt% of the filler. The PLDLLA-based composite can be an excellent candidate for bone reconstruction implants due to their superior mechanical properties, bioactivity, and complete resorbability.

Date of online publication

06.01.2022

Pages (from - to)

110997-1 - 110997-9

DOI

10.1016/j.eurpolymj.2022.110997

URL

https://www.sciencedirect.com/science/article/abs/pii/S0014305722000015

Comments

Article Number: 110997

Points of MNiSW / journal

100.0

Impact Factor

4.598 [List 2020]

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