2024

Industrial Crops and Products

Rocznik: 2024 | Tom: vol. 222, part 1

artykuł naukowy

angielski

EN The development of lignin-based materials presents a promising avenue for advancing green chemistry and mitigating environmental impact. However, the key challenge lies in the processability of lignin, which significantly affects its practical applications. Addressing the issues related to lignin's complex structure, variability, and reactivity is crucial for optimizing its incorporation into high-performance materials. Therefore, in this study we explore the efficacy of a urea-lactic acid-based deep eutectic solvent (ULA) for the dissolution of kraft lignin, aiming to enhance its practical utility in sustainable electrospinning processes, for the first time. Results of elemental analysis, IR and 2D NMR spectroscopy, provide crucial insights into the structural properties of the regenerated material post-DES treatment. The findings confirm a high lignin recovery rate, reaching up to 96.6 % for samples dissolved at 100°C. Additionally, 2D NMR analysis indicates that the process leads to partial esterification of lignin with lactate ions. The ability of the studied DES to effectively solubilize lignin underscores its potential as an efficient lignin solvent and facilitates the fabrication of lignin-based nanofibers via electrospinning. The incorporation of this DES in electrospinning processes promises significant advancements in the development of sustainable, lignin-derived materials and offers a green alternative for production of high-performance nanofibers. Preliminary results of electrochemical impedance spectroscopy and galvanostatic charge/discharge measurements confirm that the EDLC with prepared hydrogel electrolyte demonstrates attractive electrochemical properties (specific capacitance, CSP = 95 F g–1; series resistance RS = 2.2 Ω; charge transfer resistance, RCT = 1.6 Ω), which are comparable with the reference cell based on a commercial glass fibre separator. Hence, the DES-assisted-electrospinned lignin membrane can be viewed as a potential gel electrolyte matrix for practical use in construction of sustainable energy storage devices.

27.08.2024

119450-1 - 119450-14

10.1016/j.indcrop.2024.119450

https://www.sciencedirect.com/science/article/pii/S0926669024014274?dgcid=author

Article number: 119450

200

5,6 [Lista 2023]