Kinetics and thermodynamics of thermal degradation of different starches and estimation the OH group and H2O content on the surface by TG/DTG-DTA
[ 1 ] Instytut Chemii i Elektrochemii Technicznej, Wydział Technologii Chemicznej, Politechnika Poznańska | [ 2 ] Instytut Silników Spalinowych i Napędów, Wydział Inżynierii Lądowej i Transportu, Politechnika Poznańska | [ S ] student | [ P ] employee
[2.7] Civil engineering and transport[7.6] Chemical sciences
2020
scientific article
english
- starch
- TGA
- hydroxyl groups
EN The main aim of this study is to estimate the kinetic and thermodynamic parameters of thermal decomposition of starches by the Coats–Redfern method. This procedure is a commonly used thermogravimetric analysis/difference thermal gravimetry/differental thermal analysis (TG/DTG-DTA) kinetic method for single rate form. The study also shows a proposed method for reactive hydroxyl groups content on the starch surface determination, and values were in range of 960.21–1078.76 mg OH per 1 g of starch. Thermal processing revealed the thermophysical properties of biomass for the kinetics of decomposition estimation. Activation energies reached the values in range of approximately 66.5–167 kJ·mol−1. This research also enables the determination of the temperature conditions required for becoming the desired form of material. Therefore, it is necessary to achieve the requested compact porous structure in an activation process, because in the native state, the polymer exhibits limited applications as a result of thermal decomposition, low shear stress, retrogradation, and syneresis, hence the low solubility in organic solvents. Thermodynamic parameters and reactive hydroxyl groups in this article review are innovative and have not yet been found in the literature.
06.02.2020
12020357-1 - 12020357-13
Article number: 357
CC BY (attribution alone)
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final published version
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